Petroleum Science >2009, Issue 4: 421-425 DOI: https://doi.org/10.1007/s12182-009-0064-2
Influence of dissolved oxygen content on oxidative stability of linked polymer solution Open Access
文章信息
作者:Dong Zhao-xia,Lin Mei-qin,Xin Jian and Li Ming-yuan
作者单位:
Enhanced Oil Recovery Research Center, China University of Petroleum, Beijing 102249, China;Enhanced Oil Recovery Research Center, China University of Petroleum, Beijing 102249, China;Enhanced Oil Recovery Research Center, China University of Petroleum, Beijing 102249, China;Enhanced Oil Recovery Research Center, China University of Petroleum, Beijing 102249, China
投稿时间:2009-03-20
引用方式:Dong, Z., Lin, M., Xin, J. et al. Pet. Sci. (2009) 6: 421. https://doi.org/10.1007/s12182-009-0064-2
文章摘要
The influence of dissolved oxygen content on the oxidative stability of a linked polymer solution (LPS) was studied by micro-iltration, dynamic light scattering and viscosity measurements. The results showed that at the same temperature, the degree of the oxidative degradation of the LPS increased and the rapidity of the oxidative degradation was accelerated with the increase of the dissolved oxygen content. Consequently, the size of linked polymer coils (LPCs) of the LPS became small, and the plugging capability of the LPS decreased. At a fixed content of dissolved oxygen, with increasing degradation temperature, almost the same results were observed, namely, an increased degree of oxidative degradation accelerated rapidity of the oxidative degradation and decreased plugging capacity, with decreased oxidative stability of LPS. At 90 oC, in the presence of oxygen, LPS lost its plugging capability afte having been degraded for a period of time. But at 40 oC, LPS with low dissolved oxygen content could be stable for a long time. The decreased plugging ability of LPS after oxidative degradation is mainly caused by the decreased size and number of the LPCs due to the breaking of hydrolyzed polyacrylamide (HPAM molecule segments and the structural changing of HPAM molecules.
关键词
-
Linked polymer solution, HPAM, content of dissolved oxygen, degradation, stability