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Petroleum Science >2016, Issue 1: 167-172 DOI: https://doi.org/10.1007/s12182-015-0069-y

Preparation of furfural and reaction kinetics of xylose dehydration to furfural in high-temperature water Open Access

文章信息

作者：De-Run Hua,Yu-Long Wu,Yun-Feng Liu,Yu Chen,Ming-De Yang,Xin-Ning Lu and Jian Li

作者单位：

Chemical Institute of Chemical Industry, Gannan Normal University, Jiangxi 341000, China Institutes of Nuclear and New Energy Technology, Tsinghua University, Beijing 100084, China;Institutes of Nuclear and New Energy Technology, Tsinghua University, Beijing 100084, China Beijing Engineering Research Center for Biofuels, Tsinghua University, Beijing 100084, China;Institutes of Nuclear and New Energy Technology, Tsinghua University, Beijing 100084, China;Institutes of Nuclear and New Energy Technology, Tsinghua University, Beijing 100084, China;Chemical Institute of Chemical Industry, Gannan Normal University, Jiangxi 341000, China;Institutes of Nuclear and New Energy Technology, Tsinghua University, Beijing 100084, China;Institutes of Nuclear and New Energy Technology, Tsinghua University, Beijing 100084, China

投稿时间：2015-12-06

引用方式：Hua, DR., Wu, YL., Liu, YF. et al. Pet. Sci. (2016) 13: 167. https://doi.org/10.1007/s12182-015-0069-y

文章摘要

Factors in?uencing dehydration of xylose to furfural, such as catalyst and extract agents, were investigated. Results indicated that high-temperature water may substitute for solid and liquid acid as a catalyst, and ethyl butyrate improved furfural yield for the high distribution coef?cient. A furfural yield of 75 % was obtained at 200 C for 3 h in ethyl butyrate/water. The reaction kinetics of xylose dehydration to furfural was investigated and it was found that the reaction order was 0.5, and the activation energy was 68.5 kJ/mol. The rate constant k showed a clear agreement with the Arrhenius law from 160 to 200 C.

关键词

Xylose Furfural SO3H-SBA-15 Hightemperature water