欢迎访问Petroleum Science 期刊网站

首页» 往期文章» 2018» Issue 4» 石油化学与化工

Petroleum Science >2018, Issue 4: 890-897 DOI:

Synthesis of amphiphilic peroxophosphomolybdates for oxidative desulfurization of fuels in ionic liquids Open Access

文章信息

作者：Beibei Zhang, Wei Jiang, Xiaonan Fan, Ming Zhang, Yanchen Wei, Jing He, Changfeng Li, Huaming Li and Wenshuai Zhu

作者单位：

School of Energy and Power Engineering, Jiangsu University, Zhenjiang 212013, People’s Republic of China; School of Chemistry and Chemical Engineering, Yancheng Institute of Technology, Yancheng 224051, People’s Republic of China,Institute for Energy Research, Jiangsu University, Zhenjiang 212013, Jiangsu, People’s Republic of China,School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang 212013, Jiangsu, People’s Republic of China,Institute for Energy Research, Jiangsu University, Zhenjiang 212013, Jiangsu, People’s Republic of China,School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang 212013, Jiangsu, People’s Republic of China,School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang 212013, Jiangsu, People’s Republic of China,School of Energy and Power Engineering, Jiangsu University, Zhenjiang 212013, People’s Republic of China,Institute for Energy Research, Jiangsu University, Zhenjiang 212013, Jiangsu, People’s Republic of China and School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang 212013, Jiangsu, People’s Republic of China

投稿时间：2018-04-14

引用方式：

文章摘要

Three amphiphilic peroxophosphomolybdates [C₄mim]₃PMo₄O₂₄, [C₈mim]₃PMo₄O₂₄ and [C₁₆mim]₃PMo₄O₂₄ were synthesized and characterized. These catalysts were used for extraction and catalytic oxidative desulfurization of fuel with H₂O₂ as an oxidant and ionic liquid [C₄mim]BF₄ as an extractant. It was found that [C₁₆mim]₃PMo₄O₂₄ showed the highest catalytic activity and the sulfur content could decrease to 7.5 ppm. In contrast, the desulfurization system shows very low performance without H₂O₂ or ionic liquid. The detailed reaction conditions were optimized including reaction time, temperature, the dosage of H₂O₂ and catalyst, and different sulfur compounds. After the reaction, the catalysts and the ionic liquid can be cycled 8 times with a little decrease in desulfurization efficiency.

关键词

₂