Unconventional hydrocarbon resources, which are only marginally economically explored and developed by traditional methods and techniques, are different from conventional hydrocarbon resources in their accumulation mechanisms, occurrence states, distribution models, and exploration and development manners. The types of unconventional hydrocarbon are controlled by the evolution of the source rocks and the combinations of different types of unconventional reservoirs. The fundamental distinction between unconventional hydrocarbon resources and conventional hydrocarbon resources is their nonbuoyancy- driven migration. The development of the microto nano-scale pores results in rather high capillary resistance. The accumulation mechanisms of the unconventional and the conventional hydrocarbon resources are also greatly different. In conventional hydrocarbon resources, oil and gas entrapment is controlled by reservoir-forming factors and geological events, which is a dynamic balance process; while for unconventional hydrocarbon resources, the gas content is affected by the temperature and pressure fields, and their preservation is crucial. Unconventional and conventional hydrocarbons are distributed in an orderly manner in subsurface space, having three distribution models of intra-source rock, basin-centered, and source rock interlayer. These results will be of great significance to unconventional hydrocarbon exploration.