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首页» 过刊浏览» 2017» Vol. 2» Issue (4) 527-535     DOI : 10.3969/j.issn.2096-1693.2017.04.049
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多孔介质中二元复合体系乳化前后流动规律研究
刘哲宇1, 2,李宜强1, 2*,庄永涛3,陈一航4,马瑞程4
1 中国石油大学(北京)石油工程学院,北京 102249 2 中国石油大学石油工程教育部重点实验室,北京 102249 3 大港油田采油工艺研究院,天津 300280 4 中国石油大学(北京)提高采收率研究院,北京 102249
Comparison of a surfactant/polymer solution and its emulsion flowing in a porous medium
LIU Zheyu1,2, LI Yiqiang1,2, ZHUANG Yongtao3, CHEN Yihang4, MA Ruicheng4
1 College of Petroleum Engineering, China University of Petroleum-Beijing, Beijing 102249, China 2 State Key Laboratory of Petroleum Engineering, China University of Petroleum-Beijing, Beijing 102249, China 3 Oil Production Technology Institute, Dagang Oilfield Company, Tianjin 300280,China 4 Research Institute of EOR, China University of Petroleum-Beijing, Beijing 102249, China

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摘要  复合驱过程中出现的乳化现象直接影响开发效果,目前对复合体系乳化后形成的乳状液的流动规律缺少相关研究。本文采用岩心实验分别注入O/W型乳状液与等黏度的二元体系,测定采出液的流变性、粒度分布以及乳状液液滴形态,比较它们在多孔介质中的流动规律差异,再通过多孔介质模拟复合驱过程中乳状液的产生过程,通过压力变化研究各因素对体系乳化强度的影响。结果表明,二元体系乳化前后的运移规律存在明显差异,乳化前体系的压力可以很快达到平稳,而乳化后的压力呈现跳跃上升,既表现出幂律流体剪切变稀的特性,又由于分散性质加强而表现出剪切变稠的特征;采出液分析表明经过岩心后,乳状液的流变曲线上移,粒径变小,经过3 PV后乳状液的液滴形态才与初始时相似;各因素中表面活性剂浓度对乳化效果的影响大于剪切速率,含油饱和度对乳化效果的影响最小。
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关键词 : 二元复合驱, 乳状液, 渗流规律, 流变性, 多孔介质
Abstract

  The emulsion generated during combination flooding has a big impact on oil recovery. Unfortunately, there has been a lack of emulsion flow research. Core flow experiments were used to investigate the flow difference between oil in water emulsion and surfactant/polymer solution, which have the same viscosity by measuring pressure, rheological properties, particle size distribution and emulsion droplet morphology of the effluent. Meanwhile, surfactant polymer (SP) solution and oil was co-injected into a core to generate an emulsion. Impacts on emulsion flow properties, such as oil water ratio, surfactant concentration and flow velocity were investigated by comparing pressure curves. The results showed that there were significant flow differences between the SP solution and its generated emulsion. The pressure of the SP solution quickly achieved a steady level. However, the emulsion showed jamming and drop breakup phenomena. The rheology of the emulsion was not only shear thinning, but also shear thickening because pore throat shearing increased its dispersion. The analysis of effluent indicated that as the viscosity of the emulsion increased, the droplet size decreased and the emulsion morphology become similar to its initial status after 3PV. The surfactant concentration has more effect than shear rate on the emulsification, while the oil saturation has a minimal effect.

Key words: surfactant/polymer flooding emulsion percolation rule rheology porous medium
收稿日期: 2017-08-08     
PACS:    
基金资助:国家科技重大专项(2016ZX05025-003-010)和中国石油大学优秀博士学位论文基金项目(01JB0585)联合资助
通讯作者: 李宜强, lyq89731007@163.com
引用本文:   
刘哲宇,李宜强,庄永涛,陈一航,马瑞程. 多孔介质中二元复合体系乳化前后流动规律研究[J]. 石油科学通报, 2017, 2(4): 527-535. LIU Zheyu, LI Yiqiang, ZHUANG Yongtao, CHEN Yihang, MA Ruicheng. Comparison of a surfactant/polymer solution and its emulsion flowing in a porous medium. Petroleum Science Bulletin, 2017, 2(4): 527-535.
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