1 State Key Laboratory of Natural Gas Hydrate in China University of Petroleum-Beijing, Beijing 102249, China 2 National Engineering Laboratory for Pipeline Safety/ MOE Key Laboratory of Petroleum Engineering /Beijing Key Laboratory of Urban Oil and Gas Distribution Technology, China University of Petroleum-Beijing, Beijing 102249, China 3 PipeChina West East Pipeline Company, Shanghai 200122, China 4 Changqing Engineering Design Co., Ltd., Xi'an 710018, China 5 China’s Oil and Gas Exploration and Development Company, Beijing 100034, China 6 Boda oil and Gas Development Department of PetroChina Tarim Oilfield Company, Aksu 842300, China 7 CNOOC Research Institute Technology R&D Center, Beijing 100028, China
Compared with the traditional method of hydrate prevention and control in the field of multiphase gathering and
transportation in deep water, the method of adding low-dose hydrate inhibitor has significant advantages. It is favored in academic
and industrial fields at home and abroad. Anti-Agglomerant (AA) is one type of the low-dose hydrate inhibitors that can still have
good performance under more severe high undercooling conditions, which can ensure that the generated hydrate in multiphase flows
can mix with the transport fluid as slurry. In this work, the indexes for evaluating the performance of anti-agglomerants and the key
influence factors are summarized. The macro and micro characteristics of hydrate formation and the flow features of hydrate slurry
in the presence of anti-agglomerants in the system are reviewed. In general, the performance of AA is affected by its dosage, water
cut, mineralization degree and pH of the fluid, the emulsification state and subcooling degree under the application conditions. The
more stable and moderate the hydrate formation amount is, the better is the fluidity of the hydrate slurry with AA addition and the
lower the risk of hydrate blockage occurring in the multiphase flow with higher reliability of ensuring its flow safety. Based on all the
research, the mechanisms of AA are summarized. Finally, suggestions for further research on anti-agglomerants in the future are given.
Key words:hydrate; anti-agglomerants; emulsion; adsorption
Received: 2022-05-17
Corresponding Authors:bh.shi@cup.edu.cn
Cite this article:付顺康, 王智, 卫国锋, 梁璇玑, 陈玉川, 张烜玮, 姚海元, 许保珅, 宋尚飞, 史博会, 吴海浩, 宫敬. 水合物阻聚剂研究进展. 石油科 学通报, 2024, 02: 318-337 FU Shunkang, WANG Zhi, WEI Guofeng, LIANG Xuanji, CHEN Yuchuan, ZHANG Xuanwei, YAO Haiyuan, XU Baoshen, SONG Shangfei, SHI Bohui, WU Haihao, GONG Jing. Progress of hydrate Anti-Agglomerants. Petroleum Science Bulletin, 2024, 02: 318-337.
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