【工作经历】
2016.7-至今：中国石油大学（北京）化学工程与环境学院 副教授
2016.3-2016.7：中国石油大学（北京）化学工程学院 讲师
【教育经历】
2011.10-2015.12：荷兰埃因霍温理工大学 化学工程与化学学院 工学博士 导师：Prof. Dr. Ir. Emiel J. M. Hensen
2010.9-2011.10：中国石油大学（北京）化学工程学院 博士研究生 导师：申宝剑教授
2007.9-2010.7：中国石油大学（北京）化学工程学院 工学硕士 导师：徐春明院士 史权教授
2002.9-2006.7：中国石油大学（华东）化学工程学院 理学学士
【研究方向】
致力于无机多孔催化材料的制备及应用研究，结合先进的表征方法、理论建模和性能评价，指导特定功能化的固体催化材料的设计与制备。
相关的研究主要包括：
催化材料理性设计与制备
微孔多级孔沸石分子筛合成
甲醇制烯烃
甲烷活化转化
二氧化碳加氢制高值化学品
低碳烃催化裂解制低碳烯烃
深地化石能源原位催化转化
【科研项目】
2016.5-2019.6 主持中石大引进人才启动项目 (20万)
2016.9-2018.11 主持中石油十三五炼油重大科技攻关项目 (80万)
2018.1-2020.12 主持国家自然科学基金青年基金项目(28.8万)
2019.1-2021.12 主持国自然-中石油联合基金培育项目 (50.4万)
2019.10-2021.9 参与工信部工业催化服务平台建设项目 (20万)
2022.1-2025.6 参与中石油炼化国际科技合作项目 (305万)
2023.3-2025.8 主持中石油十四五重大科技攻关项目 (432万)
2025.3-2028.3 主持中石油科技创新基金项目 (50万)
【发表文章】
[33] Zhu, X.*; Gao, Y.; Chen, H.; Jiang, M.; Wang, X.; Miao, C.; Shen, Y.; Ji, Y.; Qin, Z.; Wu, Z.; Song, W.; Xu, C.; Shen, B.* Constructing hierarchical zeolites with highly complete framework via controlled desilication. Angewandte Chemie International Edition, 2024, 63, e202411446. (hot paper)
[32] 朱小春*, 张腾跃, 赵红娟, 张磊, 刘宏海, 申宝剑. ZSM-5薄层沸石协同晶化及其MTP催化性能研究. 现代化工, 2024, 44, 81.
[31] Zhu, X.*; Gao, Y.; Liu, M.; Yang, Z.; Li, S.; Chen, H.; Liu, B.; Ma, W.; Hensen, E. J. M.; Shen. B. Efficient synthesis of high-silica SSZ-13 zeolite and its catalytic performance in MTO reaction. Microporous and Mesoporous Materials, 2022, 345, 112260.
[30] Chen, K.; Zhao, J.; Li, A.; Li, G.; Zhang, Q.; Xia, T.; Zhao, H.; Zhu, X.; Liu, H.; Gao, X.; Xu, C.; Shen, B. Realumination of dealuminated HZSM-5 zeolites by acid treatment, the impact of AlF distribution and its catalytic cracking performance of alkanes. Microporous and Mesoporous Materials, 2022, 338, 111969.
[29] Chen, K.; Wu, X.; Zhao, J.; Zhao, H.; Li, A.; Zhang, Q.; Xia, T.; Liu, P.; Meng, B.; Song, W.; Zhu, X.; Liu, H.; Gao, X.; Xu, C.; Shen, B. Organic-free modulation of the framework Al distribution in ZSM-5 zeolite by magnesium participated synthesis and its impact on the catalytic cracking reaction of alkanes. Journal of Catalysis, 2022, 413, 735.
[28] Liu, B.; Zhu, X.; Zhao, J.; Wang, D.; Ma, W. A Study into the γ-Al2O3 Binder Influence on Nano-H-ZSM-5 via Scaled-Up Laboratory Methanol-to-Hydrocarbon Reaction. Catalysts, 2021, 11, 1140.
[27] 朱小春*, 李苗苗, 代跃利, 汲永钢, 申宝剑. SSZ-13沸石形貌及硅铝比对甲醇制烯烃反应性能的影响. 工业催化, 2020, 28, 28.
[26] Yu, Q.; Sun, H.; Sun, H.; Li, L.; Zhu, X.; Ren, S.; Guo, Q.; Shen, B. Highly mesoporous IM-5 zeolite prepared by alkaline treatment and its catalytic cracking performance. Microporous and Mesoporous Materials, 2019, 273, 297.
[25] Yu, Q.; Huang, Z.; Sun, H.; Li, L.; Zhu, X.; Ren, S.; Shen B. Investigation on n-Alkane Hydroisomerization, a Comparison of IM-5 to ZSM-5 Zeolites. Industrial & Engineering Chemistry Research, 2018, 57, 14448.
[24] Meng, L.; Zhu, X.; Wannapakdee, W.; Pestman, R.; Goesten, M. G.; Gao, L., van Hoof, A. J. F.; Hensen, E. J. M. A dual-templating synthesis strategy to hierarchical ZSM-5 zeolites as efficient catalysts for the methanol-to-hydrocarbons reaction. Journal of Catalysis, 2018, 361, 135.
[23] Li, C.; Guo, L.; Liu, P.; Gong, K.; Jin, W.; Li, L.; Zhu, X.; Liu, X.; Shen, B. Defects in AHFS-dealuminated Y zeolite: A crucial factor for mesopores formation in the following base treatment procedure. Microporous and Mesoporous Materials, 2018, 255, 242.
[22] Zhu, X.; Kosinov, N.; Kubarev, A. V.; Bolshakov, A.; Mezari, B.; Valastyan, I.; Hofmann, J. P.; Roeffaers, M. B. J.; Sarkadi-Pribóczki, E.; Hensen, E. J. M. Probing the Influence of SSZ-13 Zeolite Pore Hierarchy in MTO Catalysis by NASCA microscopy and Positron Emission Profiling. ChemCatChem, 2017, 9, 3470.（封面文章）
[21] Goesten, M. G.; Zhu, X.; Mezari, B.; Hensen, E. J. M. On Layered Silicates and Zeolitic Nanosheets. Angewandte Chemie International Edition. 2017, 56, 5160.
[20] Meng, L.; Zhu, X.; Hensen, E. J. M. Stable Fe/ZSM-5 Nanosheet Zeolite Catalysts for the Oxidation of Benzene to Phenol. ACS Catalysis, 2017, 7, 2709.
[19] Meng, L.; Zhu, X.; Mezari, B.; Pestman, R.; Wannpakdee, W.; Hensen, E. J. M. On the role of acidity in bulk and nanosheet [T]MFI (T = Al3+, Ga3+, Fe3+, B3+) zeolites in the methanol-to-hydrocarbons reaction. ChemCatChem, 2017, 9, 3942.
[18] Zheng, Q.; Huo, L.; Li, H.; Mi, S.; Li, X.; Zhu, X.; Deng, X.; Shen, B. Exploring structural features of USY zeolite in the catalytic cracking of Jatropha Curcas L. seed oil towards higher gasoline/diesel yield and lower CO2 emission. Fuel, 2017, 202, 563.
[17] Zeng, P.; Guo, X.; Zhu, X.; Guo, Q.; Wang, Y.; Ren, S.; Shen, B. On the synthesis and catalytic cracking properties of Al-ITQ-13 zeolites. Microporous and Mesoporous Materials, 2017, 246, 186.
[16] Li, H.; Liu, J.; Li, J.; Hu, Y.; Wang, W.; Yuan, D.; Wang, Y.; Yang, T.; Li, L.; Sun, H.; Ren, S.; Zhu, X.; Guo, Q.; Wen, X.; Li, Y.; Shen, B. Promotion of the Inactive Iron Sulfide to an Efficient Hydrodesulfurization Catalyst. ACS Catalysis, 2017, 7, 4805.
[15] Zhu, X.; Goesten, M. G.; Koekkoek, A.; Mezari, B.; Filonenko, G.; Friedrich, H.; Rohling, R.; Szyja, B. M.; Gascon, J.; Kapteijn, F.; Hensen, E. J.M. Establishing hierarchy: the chain of events leading to the formation of Silicalite-1 nanosheets. Chemical Science, 2016, 7, 6506.
[14] Zhu, X.; Hofmann, J. P.; Mezari, B.; Kosinov, N.; Wu, L.; Qian, Q.; Weckhuysen, B. M.; Asahina, S.; Ruiz-Martínez, J.; Hensen, E. J. M. Trimodal porous hierarchical SSZ-13 zeolite with improved catalytic performance in the Methanol-to-Olefins reaction. ACS Catalysis, 2016, 6, 2163.
[13] Zhu, X.; Kosinov, N.; Hofmann, J. P.; Mezari, B.; Qian, Q.; Rohling, R.; Weckhuysen, B. M.; Ruiz-Martínez, J.; Hensen, E. J. M. Fluoride-assisted synthesis of bimodal microporous SSZ-13 zeolite. Chemical Communications, 2016, 52, 3227.
[12] Yuan, D.; Kang, C.; Wang, W.; Li, H.; Zhu, X.; Wang, Y.; Gao, X.; Wang, B.; Zhao, H.; Liu, C.; Shen. B. Creation of mesostructured hollow Y zeolite by selective demetallation of an artificial heterogeneous Al distributed zeolite crystal. Catalysis Science & Technology, 2016, 6, 8364.
[11] Feng, B.; Li, J.; Zhu, X.; Guo, Q.; Zhang, W.; Wen, G.; Zhang, Z.; Gu, L.; Yang, Z.; Zhang, Q.; Shen, B. The state of iron sites in the calcined FeAlPO4-5 and its tuning to the property of microporous AlPO4-5 molecular sieve. Catalysis Today, 2016, 263, 91.
[10] Zhu, X.; Wu, L.; Magusin, P. C. M. M.; Mezari, B.; Hensen, E. J. M. On the synthesis of highly acidic nanolayered ZSM-5. Journal of Catalysis, 2015, 327, 10.
[9] Liu, P.; Zhu, X.; Yang, S.; Li, T.; Hensen, E. J. M. On the metal–support synergy for selective gas-phase ethanol oxidation over MgCuCr2O4 supported metal nanoparticle catalysts. Journal of Catalysis, 2015, 331, 138.
[8] Yue, C.; Zhu, X.; Rigutt, M.; Hensen, E. J. M. Acid catalytic properties of reduced tungsten and niobium-tungsten oxides. Applied Catalysis B: Environmental, 2015, 163, 370.
[7] Tempelman, C. H. L.; Zhu, X.; Gudun, K.; Mezari, B.; Shen, B.; Hensen, E. J. M. Texture, acidity and fluid catalytic cracking performance of hierarchical faujasite zeolite prepared by an amphiphilic organosilane. Fuel Process Technology, 2015, 139, 248.
[6] Tempelman, C. H. L.; Zhu, X.; Hensen, E. J. M. Activation of Mo/HZSM-5 for methane aromatization. Chinese Journal of Catalysis, 2015, 36, 829.
[5] Agarwal, S.; Zhu, X.; Hensen, E. J. M.; Mojet, B. L.; Lefferts, L. Surface-dependence of defect chemistry of nanostructured ceria. Journal of Physical Chemistry C, 2015, 119, 12423.
[4] Agarwal, S.; Zhu, X.; Hensen, E. J. M.; Lefferts, L.; Mojet, B. L. Defect chemistry of ceria nanorods. Journal of Physical Chemistry C, 2014, 118, 4131.
[3] Zhu, X.; Rohling, R.; Filonenko, G.; Mezari, B.; Hofmann, J. P.; Asahina, S.; Hensen, E. J. M. Synthesis of hierarchical zeolites using an inexpensive mono-quaternary ammonium surfactant as mesoporogen. Chemical Communications, 2014, 50, 14658.
[2] Wu, L.; Magusin, P. C. M. M.; Degirmenci, V.; Li, M.; Almutairi, S. M. T.; Zhu, X.; Mezari, B.; Hensen, E. J. M. Acidic properties of nanolayered ZSM-5 zeolites. Microporous and Mesoporous Materials, 2014, 189, 144.
[1] Zhu, X.; Shi, Q.; Zhang, Y.; Pan, N.; Xu, C.; Zhao, S.; Chung, K. Characterization of Nitrogen Compounds in Coker Heavy Gas Oil and Its Subfractions by Liquid Chromatographic Separation Followed by Fourier Transform Ion Cyclotron Resonance Mass Spectrometry. Energy & Fuels, 2011, 25, 281.
【专著】
[1] 参与编撰《能源转化催化原理》第二版, 中国石油大学出版社, 2022-08-30
【获奖】
[1] 中国石油和化工教育教学优秀教材,二等奖, 2024.
【授权专利】
[1] 朱小春、高羽、李苗苗. 一种甲醇制烯烃催化剂及其制备方法. 中国发明专利, 2020, 授权专利号ZL201810851043.9
[2] 朱小春、郭健、李苗苗、高羽、申宝剑. 一种多级孔ZSM-5沸石及其制备方法与应用. 中国发明专利, 2021, 授权专利号ZL201910603635.3
[3] 朱小春、李苗苗、高羽、郭健、申宝剑. SSZ-13沸石的快速可控制备方法及H-SSZ-13沸石和甲醇制烯烃催化剂. 中国发明专利, 2021, 授权专利号ZL202010016772.X
[4] 朱小春、高羽、刘孟、杨子瑶、申宝剑. 一种多级孔沸石分子筛及其制备方法和应用. 中国发明专利, 2022, 授权专利号ZL202110618130.1
[5] 朱小春、杨子瑶、李双双、申宝剑. 一种甲烷无氧芳构化催化剂及其改性制备方法. 中国发明专利, 2024, 授权专利号ZL202211317171.8
[6] 朱小春、陈皓荣、王震宇、申宝剑. 一种SSZ-13沸石催化剂及其制备方法和应用. 中国发明专利, 2025, 授权专利号ZL2023105378148
[7] 朱小春、王久江、赵红娟、张腾跃、刘宏海、申宝剑、刘超伟、方华、柳黄飞、曹庚振. 一种短b轴ZSM-5沸石及其制备方法和应用. 中国发明专利, 申请号2024116394346
[8] 朱小春、江蒙伟、王鑫雨. 一种多级孔沸石分子筛及其制备方法和应用. 中国发明专利, 申请号2024117653795
【社会兼职】
Journal of the American Chemical Society, Chemistry of Materials, ACS Catalysis, Industrial & Engineering Chemistry Research, Chinese Journal of Catalysis, Catalysis Science & Technology等化学化工及催化领域高水平SCI期刊审稿人；担任国家留学基金委评审专家、国家自然科学基金评审专家、教育部第五轮学科评估专家；工业催化联盟青年工作委员会委员；石油科学（英文版）期刊青年编委。
